Ayoknox Ventures

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Material safety data sheet DMA

1. Product and Company Name

Product

DMA
 Alternative Names: Marine Gas Oil, MGO, Gas Oil, F76, DMAXX, DMALS

Application

Fuel for diesel engines or heating/boiler plant

Company

Ayoknox ventures
 14, Itapeju Street,
 Off Wharf Road,
 Apapa,Lagos.
 Ngieria.

Emergency Telephone Number

+49 (0) 180 100 31 28

2. Composition/Information on Ingredients

Chemical Composition

Complex mixture of paraffin hydrocarbons, naphthenic, aromatic and olefin hydrocarbons, with carbon numbers in C10 to C28 range. Performance enhancing additives may be included.

Hazardous Components

Cracked components containing polycyclic aromatic hydrocarbon compounds may be present.

Fuel´s, diesel

- EINECS No: 269-822-7
 - CAS No: 68334-30-5
 - 90 % Wt

R40

Limited evidence of a carcinogenic effect

R51/53

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R65

Harmful: may cause lung damage if swallowed

R66

Repeated exposure may cause skin dryness or cracking

3. Hazards Identification

Health effects

Prolonged or repeated contact with skin destroys the lipoacid skin layer and may cause dermatitis. Vapours or mist are irritating for mucous membranes, notably in the eyes.
 If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious inhalation pulmonary lesions (medical survey during 48 hours).

Environmental impact

Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Physico-chemical hazards

The product may form flammable mixtures with air when heated above the flash point.
 In the presence of hot spots, there is a special risk of fire or explosion under certain conditions involving accidental release of vapour or leaks of hot product under pressure.

Product classification

Category 3, carcinogen
 Harmful: May cause lung damage if swallowed.
 Dangerous for the environment.

4. First Aid Measures

General

In case of serious or persistent conditions, consult a doctor or call for emergency medical aid.

Eyes

Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open for at least 15 minutes and consult a specialist.

Skin

Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and wash underlying skin.
 Medical advice must be obtained urgently if product under high pressure has been injected through the skin.

Ingestion

If contamination of the mouth occurs, wash out thoroughly with water. If larger amounts are swallowed, do not induce vomiting; transport casualty together with the product container, its label or the safety data sheet urgently to hospital.

Inhalation

If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air, keep warm and allow to rest. If symptoms persist or breathing is difficult, apply mechanical ventilation immediately and obtain medical advice.

Medical Advice

Treatment should in general be symptomatic and directed to relieving any effects.

Note: High Pressure Applications
 Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful with extensive subcutaneous necrosis.
 Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.

Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Other recommendations

Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminated clothing may be more effective than normal laundering. Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing.

5. Fire Fighting Measures

For major fires call the Fire Service.
 Ensure an escape path is always available from any fire.
 There is a danger of flashback if sparks or hot surfaces ignite vapour.

Use foam, dry powder or water fog. DO NOT USE water jets.

Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus and fire-resistant clothing.

Combustion Products

Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot (See Stability and Reactivity, Section 10). These may be highly dangerous if inhaled.

6. Accidental Release Measures

Personal protection

Evacuate all non essential personnel from the immediate area.
 If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is present before entry.
 Ensure good ventilation.
 Vapour may collect in any confined space.
 Wear protective clothing (See Exposure Controls/Personal Protection, Section 8).
 Spilled material may make surfaces slippery.

After spillage/leakage

Isolate spillage from all ignition sources including road traffic.
 Protect drains from potential spills to minimise contamination. Do not wash product into drainage system. Vapour is heavier than air and may travel to remote sources of ignition (e.g. along drainage systems, in basements etc.).
 Any spillage should be regarded as a potential fire risk.
 Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
 Spillages of hot product in confined spaces may be especially hazardous because highly toxic hydrogen sulphide gas may be present. For spillages in such confined spaces the use of approved breathing apparatus by personnel specially trained in its use may be required.
 In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect environmentally sensitive areas and water supplies.
 In the case of spillage at sea approved dispersants may be used where authorised by the appropriate government/regulatory authorities.
 In the event of spillages contact the appropriate authorities.

Spill cleanup methods

Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary, clean the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.
 Use mechanical means such as pumps, skimmers and absorbent materials. Never use dispersing agents.
 Contain and collect the spilled product with sand or any other inert absorbent material.
 It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage which may be reasonably anticipated.
 Preserve the waste in closed and sealed recipients.
 Handover contaminated materials to an approved collector.
 Recovery of large spillages should be effected by specialist personnel.

Prevention of secondary risks

Remove all sources of ignition.

7. Handling and Storage

Handling

Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
 Do not siphon product by mouth.
 Avoid contact with skin and observe good personal hygiene. Wash hands thoroughly after contact.
 Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
 Whilst using do not eat, drink or smoke.
 Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
 The product may contain volatile hydrocarbons which may accumulate in the container headspace, thereby creating a flammable or explosive atmosphere.

Storage

Store and dispense only in well ventilated areas away from heat and sources of ignition.
 Containers must be properly labelled and kept closed when not in use.
 Protect containers against static electricity, lighting and physical damage.
 Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an oxygen concentration of at least 20% volume.
 Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved type and following procedures strictly in accordance with the Statutory Regulations governing such entry (See Exposure Controls/Personal Protection, section 8).
 Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a quick rescue.

Fire Prevention

Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks.
 Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or mists generated will create a flammability or explosion hazard.
 When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
 Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use.
 Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never cut, weld, solder or braze empty containers.

8. Exposure Controls/Personal Protection

Exposure Limits

There is no appropriate occupational exposure limit for this material.
 Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
 If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest reasonably practicable level.

Protective Clothing

Wear face visor or goggles in circumstances where eye contact can accidentally occur.
 If skin contact is likely, wear impervious protective clothing and/or gloves.
 Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably starched after use.

Respiratory Protection

If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory equipment should be worn.
 The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory requirements governing its selection and use.
 Oxygen levels should be at least 19.5 % in confined spaces or other work areas.

9. Physical and Chemical Properties

Typical Values

Test Method

Units

Physical state

liquid

Colour

clear [may be dyed to comply with local regulations/ requirements]

Odour

characteristic hydrocarbon

Density @ 15°C

ASTM D 1298

kg/m³

1890 (max)

Kinematic viscosity @ 40°C

ASTM D 445

mm²/s

1.5 - 6

Flash point (PMC)

ASTM D 93

°C

60 min

10. Stability and Reactivity

Stable at ambient temperatures.
 Hazardous polymerisation reactions will not occur.

Conditions to Avoid

Sources of ignition such as naked flames, sparks, hot surfaces, static electricity.
 Avoid storage at or near flash point.

Materials to Avoid

Avoid contact with strong oxidizing agents.

Hazardous Decomposition Products

Thermal decomposition products will vary with conditions.
 Incomplete combustion will generate smoke, carbon dioxide and hazardous gases, including carbon monoxide.
 Hydrogen sulphide (H2S) may released on heating and may accumulate in confined spaces.

11. Toxicological Information

Acute

Eyes

Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.

Skin

Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to dermatitis.

Ingestion

Harmful: If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious inhalation pulmonary lesions (medical survey for 48 hours min.)

Inhalation

May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes. Exceptionally risk of hydrogen sulphide intoxication: eye irritation, nausea, headache, dizziness, loss of consciousness and death.

Chronic

As with all such products containing potentially harmful levels of PCAs/PAHs, prolonged or repeated skin contact may eventually result in dermatitis or more serious irreversible skin disorders including cancer.

12. Ecological Information

Ecotoxicity

Accute toxicity

LL50 96h fish 31 mg/l

Accute toxicity

TLm 48h Crustacea 1.6 mg/l

Accute toxicity

ILm 72h algae 20 mg/l

Mobility

Spillages may penetrate the soil causing ground water contamination. This material may accumulate in sediments.

Persistence and degradability

According to EC criteria: not readily biodegradable.

Potential to bioaccumulate

Potentially bioaccumulate.

Aquatic toxicity

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
 Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.

13. Disposal Considerations

Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed waste disposal contractor.
 At sea, used or unwanted product should be stored for eventual discharge into port approved waste oil disposal facilities.
 Empty packages may contain some remaining product. Disposal via an authorised waste contractor. Hazard warning labels are a guide to the safe handling of empty packaging and should not be removed.

14. Transport Information

Sea Transport

Flammable Liquids

IMO/IMDG

Gas oil

UN No.

1202

IMO, IMDG Class

Classification Code

Packing Group

III

Marine pollutant

EmS No

3-07

MFAG Table No

311

Hazard Label(s)

Safety Card

F-E, S-E

Road/Rail Transport

Flammable Liquids

ADR/RID

Gas oil

UN No.

1202

ADR/RID Class

Classification Code

Packing Group

III

Hazard Identification No.

CEFIC Tremcard No

UK Emergency action code

Pollutant to the aquatic Environment

Hazard Label(s)

Inland waterways

Flammable Liquids

ADNR

Gas oil

UN No.

1202

ADNR Class

Packing Group

III

Hazard Label(s)

Air Transport

Flammable liquids

IATA/ICAO

Gas oil

UN No.

1202

IATA/ICAO Class

Packing Group

III

Hazard Label(s)

15. Regulatory Information

EU Category of Danger

Carcinogenic category

3
 Harmful
 Dangerous for the environment

EU Labelling

Symbol

St. Andrew's Cross, Xn Harmful
 Dead tree and fish, N Dangerous for the environment

Risk (R) Phrases

R40

Limited evidence of a carcinogenic effect.

R51/53

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

R65

Harmful: may cause lung damage if swallowed.

R66

Repeated exposure may cause skin dryness or cracking

Safety (S) Phrases

Keep out of the reach of children

S24

Avoid contact with skin

S36/37

Wear suitable protective clothing and gloves.

S43

In case of fire, use foam, dry powder, CO2. Never use water jets.

S61

Avoid release to the environment. Refer to special instructions/safety data sheets.

S62

If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

Hazardous ingredients

Fuels, diesel

Additional Information

For non-fuel use only – 'Restricted to professional users. Attention – Avoid exposure – obtain special instructions before use.' Must be marked on packaging.

16. Other Information

Hazardous concentrations of hydrogen sulphide (H2S) gas can accumulate in storage and rundown tanks, marine vessel compartments, sump pits or other confined spaces. When opening valves, hatches and dome covers, stand upwind, keep face as far from the opening as possible and avoid breathing any gases or vapours. When exposure concentrations are unknown and respiratory protection is not used, personal H2S warning devices should be worn, These devices should not be relied on to warn of life threatening concentrations. H2S fatigues the sense of smell rapidly. The rotten egg odour of H2S disappears quickly, even though high concentrations are still present. The ACGIH TLV/TWA for H2S is 10 ppm, the STEL 15 ppm.

The company recommends that all exposures to this product be minimized by strictly adhering to recommended occupational control procedures to avoid any potential adverse health effects.

All information contained in this Material Safety Data Sheet and, in particular, the health and safety and environmental information is accurate to the best of our knowledge and belief as at the date of issue specified. However, the company makes no warranty or representation, express or implied, as to the accuracy or completeness of such information.

The provision of this Material Safety Data Sheet is not intended, of itself, to obviate the need for all users to satisfy themselves that the product described is suitable for their individual purposes and that the safety precautions and environmental advice are adequate for their individual purposes and situation. Further, it is user's obligation to use this product safely and to comply with all applicable laws and regulations concerning the use of the product.

The company accepts no responsibility for any injury, loss or damage, consequent upon any failure to follow the safety and other recommendations contained in this Material Safety Data Sheet, nor from any hazards inherent in the nature of the material, nor from any abnormal use of the material.

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